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Consider the rigorous multi-step synthesis sequence: Methyl chloride () is forcefully heated with alAmines Chemistry Question

Question

Consider the rigorous multi-step synthesis sequence: Methyl chloride ($CH_3Cl$) is forcefully heated with alcoholic $KCN$ to yield compound X. Compound X undergoes total reduction with $LiAlH_4$ to yield compound Y. Compound Y is heavily treated with a cold mixture of $NaNO_2$ and $HCl$ to yield the final major organic product Z. Identify Z.

Answer: B

💡 Solution & Explanation

$CH_3Cl$ reacts via an $S_N2$ step with $KCN$ to step up the chain, forming methyl cyanide (X, $CH_3CN$). Extensive reduction with $LiAlH_4$ transforms X completely into the primary amine ethanamine (Y, $CH_3CH_2NH_2$). Y reacts with nitrous acid to forcefully generate a highly unstable diazonium salt that collapses to an ethyl carbocation, catching water to finally yield ethyl alcohol (Z).

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