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The amine group in aniline is exceptionally activating towards electrophilic aromatic substitution. Amines Chemistry Question

Question

The amine group in aniline is exceptionally activating towards electrophilic aromatic substitution. If aniline is reacted directly with an excess of uncontrolled aqueous bromine ($Br_2/H_2O$), what is the exact identity and physical state of the major product?

Answer: C

💡 Solution & Explanation

The extreme activation caused by the highly electron-donating $-NH_2$ group completely prevents the reaction from stopping at monosubstitution. Direct aqueous bromination aggressively substitutes all available ortho and para positions simultaneously, resulting in a rapid, massive formation of 2,4,6-tribromoaniline as a characteristic white precipitate.

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