The industrial-scale preparation of aniline via the reduction of nitrobenzene heavily prefers a spec — Amines Chemistry Question
Question
The industrial-scale preparation of aniline via the reduction of nitrobenzene heavily prefers a specific reagent combination due to extreme cost efficiency. Which reagent combination is it?
Answer: C
💡 Solution & Explanation
Scrap iron ($Fe$) and $HCl$ are preferred industrially because the reduction initially forms $FeCl_2$, which undergoes subsequent rapid hydrolysis to release $HCl$ back into the reaction mixture. Because $HCl$ is continuously regenerated cyclically, only a very small, catalytic initial amount of acid is required, making the process highly economical.
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