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Alkyl isocyanides () exhibit fundamentally distinct chemical reactivity compared to alkyl cyanides (Amines Chemistry Question

Question

Alkyl isocyanides ($R-NC$) exhibit fundamentally distinct chemical reactivity compared to alkyl cyanides ($R-CN$). If methyl isocyanide ($CH_3NC$) undergoes complete chemical reduction utilizing $LiAlH_4$, what is the exact identity of the resulting amine?

Answer: D

💡 Solution & Explanation

Isocyanides feature the nitrogen atom structurally located between the alkyl chain and the terminal carbon. Complete powerful reduction utilizing $LiAlH_4$ specifically forces hydrogen onto both the carbon and the nitrogen atoms of the functional group, yielding entirely the secondary ($2^\circ$) amine, dimethylamine ($CH_3NHCH_3$).

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