What is the correct observed sequence of basic strength for strictly gas-phase, completely unsolvate β Amines Chemistry Question
Question
What is the correct observed sequence of basic strength for strictly gas-phase, completely unsolvated aliphatic amines?
Answer: A
π‘ Solution & Explanation
In the gas phase, solvent effects (like hydration stabilization and steric hindrance to solvation) are completely absent. The basic strength is dictated exclusively by the electron-donating inductive (+I) effect of the alkyl groups. More alkyl groups yield higher basicity, resulting in the strict $3^\circ > 2^\circ > 1^\circ > NH_3$ order.
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