Aldehydes Ketones and Carboxylic AcidshardMCQ SINGLE⭐ Must-Do

The melting points of the first ten aliphatic carboxylic acids exhibit an "alternation effect". Why Aldehydes Ketones and Carboxylic Acids Chemistry Question

Question

The melting points of the first ten aliphatic carboxylic acids exhibit an "alternation effect". Why do even-carbon acids melt at higher temperatures than adjacent odd-carbon acids?

Answer: B

💡 Solution & Explanation

The zig-zag structure of even-carbon chains places the terminal functional groups on opposite sides. This symmetry permits highly efficient close-packing in the solid crystal lattice, raising the melting point.

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