The melting points of the first ten aliphatic carboxylic acids exhibit an "alternation effect". Why β Aldehydes Ketones and Carboxylic Acids Chemistry Question
Question
The melting points of the first ten aliphatic carboxylic acids exhibit an "alternation effect". Why do even-carbon acids melt at higher temperatures than adjacent odd-carbon acids?
Answer: B
π‘ Solution & Explanation
The zig-zag structure of even-carbon chains places the terminal functional groups on opposite sides. This symmetry permits highly efficient close-packing in the solid crystal lattice, raising the melting point.
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