Aldehydes Ketones and Carboxylic AcidshardMCQ SINGLE⭐ Must-Do

In the mechanism of the haloform reaction of a methyl ketone, what acts as the exceptionally stable Aldehydes Ketones and Carboxylic Acids Chemistry Question

Question

In the mechanism of the haloform reaction of a methyl ketone, what acts as the exceptionally stable leaving group during the critical $C-C$ bond cleavage step?

Answer: D

💡 Solution & Explanation

After exhaustive $\alpha$ -halogenation, the $C-C$ bond is cleaved by nucleophilic attack of $OH^-$. The trihalomethyl carbanion ($CX_3^-$) is a stable leaving group because three halogens intensely stabilize the negative charge via -I effect.

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