To synthesize phenol from aniline, the amine must first be diazotized. What are the correct reagents — Alcohols Phenols and Ethers Chemistry Question
Question
To synthesize phenol from aniline, the amine must first be diazotized. What are the correct reagents and strictly required temperature range for this critical step?
Answer: A
💡 Solution & Explanation
Diazotization of primary aromatic amines utilizes nitrous acid (generated from $NaNO_2$ and $HCl$). Because the resulting diazonium salt is highly unstable, the reaction must be performed strictly in an ice bath between $273\text{ K}$ and $278\text{ K}$ ($0-5^\circ\text{C}$).
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