Arrange the following in decreasing order of their boiling points: n-Butanol, 2-Methylpropan-1-ol, 2 — Alcohols Phenols and Ethers Chemistry Question

💡 Solution & Explanation

Among isomeric alcohols, the boiling point decreases with an increase in branching because the surface area decreases, leading to weaker van der Waals dispersion forces. Thus, straight-chain n-butanol has the highest boiling point.