Alcohols Phenols and EthershardMCQ SINGLE⭐ Must-Do

Halogenation of phenol yields vastly different products depending on the polarity of the solvent. WhAlcohols Phenols and Ethers Chemistry Question

Question

Halogenation of phenol yields vastly different products depending on the polarity of the solvent. What is the major organic product formed when phenol reacts with bromine in a non-polar solvent like $CS_2$ at low temperature ($273\text{ K}$)?

Answer: B

💡 Solution & Explanation

In non-polar solvents at low temperatures, the activation of the benzene ring is moderately controlled. Monobromination occurs, yielding a mixture of ortho and para isomers. Due to less steric hindrance, p-bromophenol is the major product.

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