Alcohols Phenols and EthershardMCQ SINGLE⭐ Must-Do

When acetaldehyde () is subjected to reduction using lithium aluminium deuteride () followed by an aAlcohols Phenols and Ethers Chemistry Question

Question

When acetaldehyde ($CH_3CHO$) is subjected to reduction using lithium aluminium deuteride ($LiAlD_4$) followed by an aqueous workup with standard water ($H_2O$), what is the major organic product formed?

Answer: B

💡 Solution & Explanation

The reduction of a carbonyl group by $LiAlD_4$ involves the nucleophilic attack of a deuteride ion ($D^-$) on the carbonyl carbon, forming an alkoxide intermediate ($CH_3-CH(D)-O^-$). Subsequent hydrolysis with $H_2O$ provides a proton ($H^+$) to the oxygen, yielding $CH_3CHDOH$.

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