States of Matter and Gaseous StatemediumMCQ SINGLE

The closed containers of the same capacity and at the same temperature are filled with 44g of in oneStates of Matter and Gaseous State Chemistry Question

Question

The closed containers of the same capacity and at the same temperature are filled with 44g of $H_2$ in one and 44g of $CO_2$ in the other. If the pressure of carbon dioxide in the second container is 1 atm. That of hydrogen in the first container would be :

Answer: C

💡 Solution & Explanation

# Solution **Step 1: Find the number of moles in each container** For $H_2$: $$n_{H_2} = \frac{44 \text{ g}}{2 \text{ g/mol}} = 22 \text{ mol}$$ For $CO_2$: $$n_{CO_2} = \frac{44 \text{ g}}{44 \text{ g/mol}} = 1 \text{ mol}$$ **Step 2: Apply ideal gas law** Since both containers have: - Same volume ($V$) - Same temperature ($T$) - Same capacity Using $PV = nRT$, we get: $$P = \frac{nRT}{V}$$ Therefore, pressure is directly proportional to the number of moles: $$\frac{P_{H_2}}{P_{CO_2}} = \frac{n_{H_2}}{n_{CO_2}}$$ **Step 3: Calculate pressure of hydrogen** $$\frac{P_{H_2}}{1 \text{ atm}} = \frac{22}{1}$$ $$P_{H_2} = 22 \text{ atm}$$ **Answer: The pressure of hydrogen in the first container is 22 atm** (Option C) The key insight is that at constant V and T, pressure depends only on the number of moles—even though $H_2$ and $CO_2$ have different molar masses, the 44g of $H_2$ contains 22 times more moles than 44g of $CO_2$, producing 22 times higher pressure.

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