Coordination CompoundsmediumMCQ SINGLE

Amongst[ Ni (CO)4], [Ni (CN)4]2– and []2Coordination Compounds Chemistry Question

Question

Amongst[ Ni (CO)4], [Ni (CN)4]2– and [$NiCl_4$]2

Answer: C

💡 Solution & Explanation

4 1.[Ni(CO) ],Ni=0 8 2 2- 4 +2 8 2- 4 +2 8 Ni=[Ar]3d 4s 2.[Ni(CN) ] ,Ni=+2 Ni =[Ar]3d 3.[NiCl ] ,Ni=+2 Ni =[Ar]3d CO and CN- are strong filed ligands Hence, both the complexes are diamagnetic in nature whereas Cl- is a weak field ligand, Hence, this complex is paramagnetic. Hence, the correct answer is option (c)

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