Haloalkanes and HaloareneshardMCQ SINGLE

During the final critical nucleophilic cleavage step of the classic haloform reaction performed on aHaloalkanes and Haloarenes Chemistry Question

Question

During the final critical nucleophilic cleavage step of the classic haloform reaction performed on a generic methyl ketone, what specific intermediate strictly acts as the expelled leaving group?

Answer: B

💡 Solution & Explanation

Following exhaustive alpha-halogenation, the hydroxide nucleophile safely attacks the active carbonyl carbon, forming a tetrahedral intermediate. This complex collapses by strictly and uniquely expelling a trihalomethyl carbanion ($-CX_3$). This specific carbanion is exceptionally stable due to the massive $-I$ (inductive) electron-withdrawing effects of the three bound halogens, allowing it to act as a viable leaving group.

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