Haloalkanes and HaloarenesmediumMCQ SINGLE

In the strict fundamental study of electrophilic aromatic substitution, which of the following speciHaloalkanes and Haloarenes Chemistry Question

Question

In the strict fundamental study of electrophilic aromatic substitution, which of the following specific substituent groups is uniquely fully characterized as being chemically overall deactivating towards the entire ring, yet strictly ortho/para-directing for all incoming electrophiles?

Answer: C

💡 Solution & Explanation

Standard halogens ($-F, -Cl, -Br, -I$) specifically act as highly unique substituents perfectly cleanly exhibiting dual behaviors. They heavily physically withdraw structural electron density fully inductively ($-I$ effect), rendering the ring solidly deactivated. Simultaneously, their lone pairs safely heavily smoothly donate electron density selectively via resonance ($+M$ effect), cleanly smoothly stabilizing the intermediate ortho/para sigma complexes.

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