The presence of an electron-withdrawing group at which position(s) with respect to the halogen most — Haloalkanes and Haloarenes Chemistry Question
Question
The presence of an electron-withdrawing $-NO_2$ group at which position(s) with respect to the halogen most effectively facilitates the $S_NAr$ reaction?
Answer: D
💡 Solution & Explanation
The $-NO_2$ group withdraws electron density via the $-M$ (mesomeric) effect. This effectively stabilizes the intermediate carbanion strictly when the $-NO_2$ group is located at the ortho or para positions relative to the leaving halogen.
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