Haloalkanes and HaloareneshardMCQ SINGLE

Which of the following analytical statements completely contradicts the fundamental thermodynamic anHaloalkanes and Haloarenes Chemistry Question

Question

Which of the following analytical statements completely contradicts the fundamental thermodynamic and stereochemical principles of the $S_N1$ mechanism?

Answer: C

💡 Solution & Explanation

The $S_N1$ mechanism involves the separation of charge in the rate-determining step to form a carbocation and a halide ion. This ionization strictly requires highly polar protic solvents (like water or alcohols) that can effectively solvate and stabilize both the developing positive and negative charges. Non-polar aprotic solvents like benzene completely fail to stabilize these ions, massively increasing the activation energy and suppressing the $S_N1$ pathway.

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