Haloalkanes and HaloarenesmediumNUMERICAL

Consider the complete, chemically balanced equation representing the formation of benzenediazonium cHaloalkanes and Haloarenes Chemistry Question

Question

Consider the complete, chemically balanced equation representing the formation of benzenediazonium chloride directly from aniline, sodium nitrite, and hydrochloric acid under ice-cold conditions. How many total moles of water ($H_2O$) are formally produced as a byproduct per single mole of aniline consumed?

Answer: 2

💡 Solution & Explanation

The diazotization of a primary aromatic amine requires nitrous acid ($HNO_2$), which is unstable and generated *in situ* from sodium nitrite and a strong mineral acid. The overall balanced chemical equation is: $C_6H_5NH_2 + NaNO_2 + 2HCl \xrightarrow{0-5^\circ C} C_6H_5N_2^+Cl^- + NaCl + 2H_2O$. Thus, exactly $2$ moles of water are produced for every mole of aniline reacted.

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