Solutions and Colligative PropertieshardMCQ MULTIPLE

For an arbitrary electrolyte with the general chemical formula undergoing partial dissociation in soSolutions and Colligative Properties Chemistry Question

Question

For an arbitrary electrolyte with the general chemical formula $A_x B_y$ undergoing partial dissociation in solution with a degree of dissociation $\alpha$, which of the following mathematical relationships are universally correct?

Answer: A,C

💡 Solution & Explanation

The dissociation reaction is $A_x B_y \rightleftharpoons x A^{y+} + y B^{x-}$. The total number of ions produced per formula unit is $n = x + y$. The van't Hoff factor definition is $i = 1 + \alpha(n - 1)$. Substituting $n = x+y$ gives $i = 1 + \alpha(x + y - 1)$ (Option A). Rearranging this equation to isolate $\alpha$ yields exactly $\alpha = \frac{i - 1}{x + y - 1}$ (Option C).

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