Solutions and Colligative PropertieshardMCQ MULTIPLE

An experimental apparatus consists of two isolated compartments separated by a perfect semipermeableSolutions and Colligative Properties Chemistry Question

Question

An experimental apparatus consists of two isolated compartments separated by a perfect semipermeable membrane (SPM). Side X is filled with $0.10\text{ M } NaCl$ (assume $100\%$ ionized) and Side Y is filled with $0.08\text{ M } BaCl_2$ (assume $100\%$ ionized). Which of the following thermodynamic and osmotic deductions are scientifically accurate?

Answer: A,B,D

💡 Solution & Explanation

The effective particle concentration (osmolarity) dictates osmotic pressure ($\pi = iCRT$). For $NaCl$ ($n=2$), osmolarity = $2 \times 0.10 = 0.20\text{ osmol L}^{-1}$ (A). For $BaCl_2$ ($n=3$), osmolarity = $3 \times 0.08 = 0.24\text{ osmol L}^{-1}$ (B). Since Side Y has a higher effective concentration ($0.24 > 0.20$), Side Y is hypertonic, and Side X is hypotonic (making C false). Osmosis always drives solvent from the hypotonic side to the hypertonic side to dilute it, so water moves from X to Y (D).

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