Solutions and Colligative PropertieshardMCQ MULTIPLE

Based on the nature of their intermolecular forces, which of the following liquid mixtures will consSolutions and Colligative Properties Chemistry Question

Question

Based on the nature of their intermolecular forces, which of the following liquid mixtures will consistently exhibit a positive deviation from Raoult's law?

Answer: A,B,D

💡 Solution & Explanation

Positive deviations occur when A-B forces are weaker than A-A/B-B forces. Adding non-polar cyclohexane to polar ethanol breaks ethanol's H-bonds. Adding non-polar $CS_2$ to polar acetone breaks dipole interactions. Adding $CCl_4$ to methanol breaks methanol's H-bonds. Benzene and toluene (C) form an ideal solution.

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