Solutions and Colligative PropertiesmediumMCQ SINGLE

When exactly of liquid A and of liquid B are mixed to form a non-ideal solution exhibiting a confirmSolutions and Colligative Properties Chemistry Question

Question

When exactly $100\text{ mL}$ of liquid A and $100\text{ mL}$ of liquid B are mixed to form a non-ideal solution exhibiting a confirmed negative deviation, what will be the thermodynamic outcome for the final total volume of the solution ($V_{final}$)?

Answer: C

💡 Solution & Explanation

For a non-ideal solution showing a negative deviation, the A-B attractive forces are stronger than the pure A-A and B-B forces. This pulls the molecules closer together, resulting in a volume contraction. Thus, $\Delta V_{mix} < 0$, meaning the final volume will be less than the sum of the pure volumes ($< 200\text{ mL}$).

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