Redox Reactions and Volumetric AnalysishardNUMERICAL

How many of the following elements undergo disproportionation when reacted with an alkaline () mediuRedox Reactions and Volumetric Analysis Chemistry Question

Question

How many of the following elements undergo disproportionation when reacted with an alkaline ($OH^-$) medium? $Cl_2$, $P_4$, $S_8$, $F_2$, $I_2$

Answer: 4

💡 Solution & Explanation

Chlorine ($Cl_2 \rightarrow Cl^- + ClO^-/ClO_3^-$), Phosphorus ($P_4 \rightarrow PH_3 + H_2PO_2^-$), Sulphur ($S_8 \rightarrow S^{2-} + S_2O_3^{2-}$), and Iodine all undergo disproportionation in alkali. Fluorine ($F_2$) is an exception; as the most electronegative element, it only gets reduced (to $F^-$) and never oxidized. Total = 4.

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