Reaction MechanismhardMCQ SINGLE

Considering the addition of carbenes to alkenes, which of the following statements correctly distingReaction Mechanism Chemistry Question

Question

Considering the addition of carbenes to alkenes, which of the following statements correctly distinguishes between singlet and triplet carbenes?

Answer: C

💡 Solution & Explanation

A singlet carbene has paired electrons in a single orbital, allowing for a concerted, stereospecific addition across the $\pi$ -bond of an alkene, preserving the original stereochemistry (cis/trans). A triplet carbene behaves as a diradical, adding in two distinct steps. The intermediate diradical can undergo bond rotation before ring closure, leading to a loss of original stereochemistry (non-stereospecific).

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