Reaction MechanismhardMCQ SINGLE

In the addition of hypochlorous acid () to propene, which of the following represents the major prodReaction Mechanism Chemistry Question

Question

In the addition of hypochlorous acid ($HOCl$) to propene, which of the following represents the major product and the correct attacking electrophile?

Answer: A

💡 Solution & Explanation

In $HOCl$, the chlorine atom is less electronegative than oxygen, generating a $Cl^+$ electrophile and an $OH^-$ nucleophile. The $Cl^+$ attacks the alkene first to form the more stable secondary carbocation intermediate at the central carbon (Markovnikov's rule). Subsequent attack by $OH^-$ on this secondary carbocation yields 1-chloro-2-propanol ($CH_3-CH(OH)-CH_2Cl$) as the major product.

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