Practical Organic Chemistry and PurificationhardMCQ SINGLE

When both nitrogen and sulphur are present in an organic compound, Lassaigne's test yields a blood-rPractical Organic Chemistry and Purification Chemistry Question

Question

When both nitrogen and sulphur are present in an organic compound, Lassaigne's test yields a blood-red coloration instead of Prussian blue upon the addition of $Fe^{3+}$ ions. This is due to the formation of:

Answer: A

💡 Solution & Explanation

When both N and S are present, sodium fusion forms sodium thiocyanate ($NaSCN$). The addition of $Fe^{3+}$ ions reacts with $SCN^-$ to form the blood-red complex iron(III) thiocyanate, $Fe(SCN)_3$ or $[Fe(SCN)]^{2+}$.

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