When both nitrogen and sulphur are present in an organic compound, Lassaigne's test yields a blood-r β Practical Organic Chemistry and Purification Chemistry Question
Question
When both nitrogen and sulphur are present in an organic compound, Lassaigne's test yields a blood-red coloration instead of Prussian blue upon the addition of $Fe^{3+}$ ions. This is due to the formation of:
Answer: A
π‘ Solution & Explanation
When both N and S are present, sodium fusion forms sodium thiocyanate ($NaSCN$). The addition of $Fe^{3+}$ ions reacts with $SCN^-$ to form the blood-red complex iron(III) thiocyanate, $Fe(SCN)_3$ or $[Fe(SCN)]^{2+}$.
π¬Ask on WhatsApp β
Still have doubts about this question?
Send it to our AI chemistry tutor on WhatsApp β gets answered in minutes