Mole Concept and Some Basic Concepts of ChemistryhardMCQ SINGLE

The absolute density of atmospheric air is measured to be at standard temperature and pressure (STP)Mole Concept and Some Basic Concepts of Chemistry Chemistry Question

Question

The absolute density of atmospheric air is measured to be $0.001293\text{ g/cm}^3$ at standard temperature and pressure (STP). Based on this data, identify the correct statement regarding its vapour density.

Answer: A

💡 Solution & Explanation

Step 1: Convert absolute density to standard units. $0.001293\text{ g/cm}^3 = 1.293\text{ g/L}$. Step 2: Calculate the average molar mass of air. At STP, $1\text{ mole}$ occupies $22.4\text{ L}$. Molar Mass = $1.293\text{ g/L} \times 22.4\text{ L/mol} = 28.96\text{ g/mol}$. Step 3: Calculate standard vapour density (relative to hydrogen). $V.D. = \frac{\text{Molar Mass}}{2} = \frac{28.96}{2} = 14.48$. Option B is incorrect because air is a mixture, so $28.96$ is its *average* molar mass, not a true molecular weight.

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