Isomerism and StereochemistryhardMCQ MULTIPLE

Prior to stereoisomer calculation, it is absolutely critical to classify a molecule's symmetry. WhicIsomerism and Stereochemistry Chemistry Question

Question

Prior to stereoisomer calculation, it is absolutely critical to classify a molecule's symmetry. Which of the following specific molecular structures are strictly classified as UNSYMMETRICAL, directly warranting the use of the $2^n$ formula?

Answer: A,B,C

💡 Solution & Explanation

An unsymmetrical molecule lacks identical terminal ends and possesses no internal plane or center of symmetry. Molecule A has ends $-CH(OH)CH_3$ and $-CH(Cl)CH_3$ (different). Molecule B has ends $-CH_3$ and $-Cl$ (different). Molecule C (an aldose) has ends $-CH_2OH$ and $-CHO$ (different). Molecule D, however, is symmetrically identical from both ends, making it symmetrical and requiring different formulas.

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