An unknown organic hydrocarbon, identified strictly as an alkane, exhibits clear optical activity. W — Isomerism and Stereochemistry Chemistry Question
Question
An unknown organic hydrocarbon, identified strictly as an alkane, exhibits clear optical activity. What is the absolute minimum number of carbon atoms this alkane must structurally possess?
Answer: C
💡 Solution & Explanation
For an acyclic alkane to be chiral, it must contain a chiral stereocenter. The smallest possible groups to attach to a central chiral $sp^3$ carbon without duplicating any are Hydrogen (0 carbons), Methyl (1 carbon), Ethyl (2 carbons), and Propyl (3 carbons). Adding the central chiral carbon itself gives a minimum total of $0 + 1 + 2 + 3 + 1 = 7$ carbon atoms (e.g., 3-methylhexane).
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