Isomerism and StereochemistryhardMCQ MULTIPLE

Which of the following specific molecular setups will definitively FAIL to exhibit macroscopic GeomeIsomerism and Stereochemistry Chemistry Question

Question

Which of the following specific molecular setups will definitively FAIL to exhibit macroscopic Geometrical Isomerism?

Answer: B,D

💡 Solution & Explanation

Setup A is a 3-bond odd cumulene, which maintains co-planar ends and shows GI. Setup C is a square planar triphenyl system, which forces all three rings into the same plane, successfully showing GI. However, Setup B is a 2-bond even cumulene (allene), ending in perpendicular planes (no GI). Setup D is a heavily hindered biphenyl forced into orthogonal perpendicular planes to relieve steric strain, rendering cis/trans measurement impossible (no GI).

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