Ionic EquilibriumhardMCQ SINGLE

An acid-base indicator has a dissociation constant . The acid form of the indicator is red and the bIonic Equilibrium Chemistry Question

Question

An acid-base indicator has a dissociation constant $K_a = 1.0 \times 10^{-5}$. The acid form of the indicator is red and the basic form is blue. Calculate the exact pH change required to alter the colour of the indicator from 80% red to 80% blue.

Answer: A

💡 Solution & Explanation

The dissociation of the indicator is $HIn \rightleftharpoons H^+ + In^-$. The pH is given by the Henderson-Hasselbalch equation: $pH = pK_{In} + \log\frac{[In^-]}{[HIn]}$. For 80% red (acid form), $pH_1 = 5 + \log(20/80) = 5 - 0.60 = 4.40$. For 80% blue (basic form), $pH_2 = 5 + \log(80/20) = 5 + 0.60 = 5.60$. The required pH change is $\Delta pH = 5.60 - 4.40 = 1.20$.

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