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Heterocyclic compounds contain atoms other than carbon within the ring structure. Which of the folloHydrocarbons Chemistry Question

Question

Heterocyclic compounds contain atoms other than carbon within the ring structure. Which of the following heteroaromatic cyclic systems are planar, exhibit $(4n+2)$ $\pi$ delocalization, and are formally aromatic?

Answer: A,B,C

💡 Solution & Explanation

(A) Pyridine is a 6-membered planar ring with 3 double bonds (6 $\pi$ $e^-$); the nitrogen's lone pair is orthogonal to the $\pi$ system. (B) Pyrrole is a 5-membered planar ring where nitrogen's lone pair is heavily delocalized into the ring to provide the needed 6 $\pi$ electrons. (C) Thiophene similarly utilizes a lone pair on sulfur to attain 6 $\pi$ electrons. (D) Piperidine is a fully saturated, non-planar aliphatic ring, lacking any $\pi$ conjugation entirely.

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