HydrocarbonshardMCQ SINGLE

An unknown alkyne '' reacts with ammoniacal cuprous chloride () solution to form a distinct red precHydrocarbons Chemistry Question

Question

An unknown alkyne '$X$' reacts with ammoniacal cuprous chloride ($Cu_2Cl_2$) solution to form a distinct red precipitate. Which of the following compounds could be '$X$'?

Answer: C

💡 Solution & Explanation

Ammoniacal cuprous chloride ($Cu_2Cl_2 + NH_4OH$) is used as a test for terminal alkynes. The $sp$ -hybridized carbon has an acidic proton that is replaced by copper to form a red copper acetylide precipitate. Internal alkynes (like But-2-yne, Pent-2-yne, Hex-3-yne) lack an acidic terminal hydrogen and do not react. Propyne is a terminal alkyne.

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