HydrocarbonshardMCQ SINGLE

When n-hexane is treated with a mixture of sulphur dioxide () and chlorine () in the presence of ultHydrocarbons Chemistry Question

Question

When n-hexane is treated with a mixture of sulphur dioxide ($SO_2$) and chlorine ($Cl_2$) in the presence of ultraviolet light, a specific substitution reaction occurs to modify the alkane. What is the name of this reaction and its primary organic product?

Answer: B

💡 Solution & Explanation

The reaction of an alkane with a mixture of $SO_2$ and $Cl_2$ under UV light or heat leads to the replacement of a hydrogen atom by a sulphonyl chloride group ($-SO_2Cl$). This free-radical substitution is known as the Reed reaction, or chlorosulphonation, producing alkylsulphonyl chlorides.

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