HydrocarbonshardMCQ SINGLE

Based on the relative electronegativities of carbon atoms with different hybridizations, which of thHydrocarbons Chemistry Question

Question

Based on the relative electronegativities of carbon atoms with different hybridizations, which of the following hydrocarbons is expected to have the highest dipole moment?

Answer: A

💡 Solution & Explanation

The dipole moment of an alkyne is greater than that of an analogous alkene because the $sp$ hybridized carbon in the triple bond has more s-character (50%) and is therefore more electronegative than an $sp^2$ or $sp^3$ carbon. This polarizes the $sp-sp^3$ carbon-carbon bond. But-1-yne has a net dipole moment ($\approx 0.8$ D) higher than but-1-ene ($\approx 0.3$ D), whereas the symmetrical but-2-yne has a zero dipole moment.

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