Consider the following alkenes: (I) , (II) , (III) . What is the correct decreasing order of their h — GOC and Organic Chemistry Basics Chemistry Question
Question
Consider the following alkenes: (I) $(CH_3)_2C=C(CH_3)_2$, (II) $CH_3-CH=CH-CH_3$, (III) $CH_2=CH_2$. What is the correct decreasing order of their heat of hydrogenation per mole?
Answer: B
💡 Solution & Explanation
The heat of hydrogenation is inversely proportional to the thermodynamic stability of the alkene. Alkene stability increases with the number of $\alpha$ -hydrogens due to hyperconjugation. (I) has 12 $\alpha$ -H, (II) has 6 $\alpha$ -H, and (III) has 0 $\alpha$ -H. Stability order is I > II > III, making the heat of hydrogenation order III > II > I.
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