The correct order of basic strength of the following amines strictly in the gaseous phase is: β GOC and Organic Chemistry Basics Chemistry Question
Question
The correct order of basic strength of the following amines strictly in the gaseous phase is:
Answer: A
π‘ Solution & Explanation
In the gaseous phase, there are no solvation (hydration) effects to stabilize the conjugate acid. Basic strength relies entirely on the $+I$ effect of the alkyl groups pushing electron density onto the nitrogen atom. Thus, a tertiary amine (three $+I$ groups) is the strongest base.
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