ElectrochemistryhardMCQ SINGLE

Given the following standard oxidation potentials (): ; . Based on these thermodynamic values, the sElectrochemistry Chemistry Question

Question

Given the following standard oxidation potentials ($E^\circ_{ox}$): $[Fe(CN)_6]^{4-} \rightarrow [Fe(CN)_6]^{3-} + e^-, E^\circ = -0.35\text{ V}$; $Fe^{2+} \rightarrow Fe^{3+} + e^-, E^\circ = -0.77\text{ V}$. Based on these thermodynamic values, the strongest oxidizing agent among the species listed is:

Answer: D

💡 Solution & Explanation

The provided values are oxidation potentials. Converting them to standard reduction potentials ($E^\circ_{red}$) by reversing the sign gives $+0.35\text{ V}$ for $[Fe(CN)_6]^{3-} \rightarrow [Fe(CN)_6]^{4-}$ and $+0.77\text{ V}$ for $Fe^{3+} \rightarrow Fe^{2+}$. The species with the highest positive standard reduction potential is the strongest oxidizing agent. Thus, $Fe^{3+}$ is the strongest oxidizing agent.

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