d and f Block ElementshardMCQ MULTIPLE

Regarding the coloration and magnetic properties of aqueous lanthanoid ions (), which of the followid and f Block Elements Chemistry Question

Question

Regarding the coloration and magnetic properties of aqueous lanthanoid ions ($Ln^{3+}$), which of the following statements are chemically accurate?

Answer: A,B,D

💡 Solution & Explanation

$La^{3+}$ ($4f^0$) and $Lu^{3+}$ ($4f^{14}$) have no unpaired f-electrons to undergo transitions, making them colourless and diamagnetic. The colour in other ions arises from $f-f$ transitions. Because they contain unpaired electrons, all other $Ln^{3+}$ ions are paramagnetic, not diamagnetic. $Gd^{3+}$ ($4f^7$) has exactly $7$ unpaired electrons, the absolute maximum.

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