While is the dominant and universally stable oxidation state for the inner transition elements, cert — d and f Block Elements Chemistry Question
Question
While $+3$ is the dominant and universally stable oxidation state for the inner transition elements, certain specific Lanthanides exhibit highly stable $+2$ or $+4$ states to achieve extraordinary quantum mechanical stability. Which of the following ions perfectly utilize this principle?
💡 Solution & Explanation
The variability of oxidation states in Lanthanides ($+2, +4$) occurs almost exclusively when the resulting ion can achieve an $f^0$ (empty), $f^7$ (half-filled), or $f^{14}$ (fully filled) subshell. $Ce^{4+}$ ($Z=58$) is $4f^0$. $Yb^{2+}$ ($Z=70$) is $4f^{14}$. $Eu^{2+}$ ($Z=63$) is $4f^7$. $Tb^{4+}$ ($Z=65$, ground state $[Xe] 4f^9 6s^2$) loses 4 electrons to become exactly $4f^7$. All statements are absolutely correct.