In the qualitative analysis detection of , a rosy-red precipitate is formed. The complex exhibits extraordinary stability. This extra stability is primarily attributed to:

Question

In the qualitative analysis detection of $Ni^{2+}$, a rosy-red precipitate is formed. The complex $[Ni(dmg)_2]$ exhibits extraordinary stability. This extra stability is primarily attributed to:

Prashant Kotian · Accepted Answer

Correct answer: D. The rosy-red precipitate of bis(dimethylglyoximato)nickel(II) is a square planar complex. Its exceptional stability arises because the two ligands form strong intramolecular hydrogen bonds (O-H...O) between themselves, effectively locking the complex into a stable pseudo-macrocyclic ring system.

💡 Solution & Explanation

Practice 22,000+ questions like this