Assuming , for which of the following gaseous equilibrium reactions is ? — Chemical Equilibrium Chemistry Question
Question
Assuming $RT > 1$, for which of the following gaseous equilibrium reactions is $K_p > K_c$?
Answer: B
💡 Solution & Explanation
From the relation $K_p = K_c(RT)^{\Delta n_g}$, for $K_p$ to be strictly greater than $K_c$ when $RT > 1$, the exponent $\Delta n_g$ must be positive ($\Delta n_g > 0$). In the dissociation of $PCl_5$, $\Delta n_g = (1 + 1) - 1 = 1$, making $K_p > K_c$.
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