Chemical BondinghardNUMERICAL

How many distinct nodal planes are present in a antibonding molecular orbital?Chemical Bonding Chemistry Question

Question

How many distinct nodal planes are present in a $\pi^* 2p_x$ antibonding molecular orbital?

Answer: 2

💡 Solution & Explanation

A $\pi$ bonding molecular orbital has one nodal plane (the plane containing the internuclear axis, where the atomic p-orbital nodes lie). A $\pi^*$ antibonding molecular orbital possesses that same planar node, plus an additional perpendicular nodal plane situated directly between the two nuclei where the out-of-phase lobes destructively interfere. Total = 2.

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