Chemical BondinghardMCQ SINGLE

Which of the following overlapping combinations is correctly matched with the type of coordinate bacChemical Bonding Chemistry Question

Question

Which of the following overlapping combinations is correctly matched with the type of coordinate back-bond it generates (assuming optimal internuclear axis)?

Answer: B

💡 Solution & Explanation

A $p\pi-d\pi$ bond requires lateral overlap between a $p$ -orbital and a $d$ -orbital. If the internuclear axis is the x-axis, the $p_y$ orbital and $d_{xy}$ orbital lie in parallel planes and their respective lobes can overlap laterally to form a $\pi$ -bond. The $d_{z^2}$ orbital typically forms $\sigma$ bonds, and $s$ -orbitals cannot form $\pi$ bonds.

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