Atomic StructurehardMCQ SINGLE

What is the ratio of the difference in energy between the first and second Bohr orbit to the differeAtomic Structure Chemistry Question

Question

What is the ratio of the difference in energy between the first and second Bohr orbit to the difference in energy between the second and third Bohr orbit in a hydrogen atom?

Answer: B

💡 Solution & Explanation

The energy difference between orbits $n_1$ and $n_2$ is proportional to $(\frac{1}{n_1^2} - \frac{1}{n_2^2})$. Between $1^{st}$ and $2^{nd}$ orbits: $\Delta E_{1,2} \propto (\frac{1}{1^2} - \frac{1}{2^2}) = \frac{3}{4}$. Between $2^{nd}$ and $3^{rd}$ orbits: $\Delta E_{2,3} \propto (\frac{1}{2^2} - \frac{1}{3^2}) = \frac{1}{4} - \frac{1}{9} = \frac{5}{36}$. Ratio $= \frac{3/4}{5/36} = \frac{3}{4} \times \frac{36}{5} = \frac{27}{5}$.

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