How many electrons does the heteroatom (Nitrogen) exclusively contribute to the continuous, delocali — Aromatic Hydrocarbons Chemistry Question
Question
How many electrons does the heteroatom (Nitrogen) exclusively contribute to the continuous, delocalized $\pi$ -electron system of the aromatic ring in a molecule of pyridine?
Answer: 1
💡 Solution & Explanation
In pyridine, the nitrogen atom is $sp^2$ hybridized. It uses two $sp^2$ orbitals for $\sigma$ bonds to adjacent carbon atoms, and the third $sp^2$ orbital holds its lone pair (which lies perfectly in the plane of the ring, orthogonal to the $\pi$ -system). Therefore, only the single unhybridized $p$ -orbital of nitrogen contributes exactly 1 electron to the aromatic $6\pi$ electron system.
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