Why do amines generally have lower boiling points than their corresponding alcohols of comparable mo — Amines Chemistry Question
Question
Why do amines generally have lower boiling points than their corresponding alcohols of comparable molecular weight?
Answer: C
💡 Solution & Explanation
Alcohols have an oxygen atom which is significantly more electronegative than the nitrogen atom in amines. This makes the $O-H$ bond more polar than the $N-H$ bond, resulting in much stronger intermolecular hydrogen bonding in alcohols compared to amines.
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