Decarboxylation typically requires harsh conditions like soda lime () and heat. However, certain car β Aldehydes Ketones and Carboxylic Acids Chemistry Question
Question
Decarboxylation typically requires harsh conditions like soda lime ($NaOH/CaO$) and heat. However, certain carboxylic acids undergo spontaneous decarboxylation upon simple gentle heating. Which of the following acids possess this property?
Answer: A,B,C
π‘ Solution & Explanation
Gem-dicarboxylic acids, $\beta$ -keto acids, and $\beta,\gamma$ -unsaturated acids possess structural features that allow for stable, concerted transition states (often 6-membered), lowering the activation energy so they easily decarboxylate upon simple heating. Simple aliphatic acids require soda lime.
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