Haloalkanes and HaloarenesmediumMCQ SINGLE

Why are aryl halides significantly less reactive than alkyl halides towards nucleophilic substitutioHaloalkanes and Haloarenes Chemistry Question

Question

Why are aryl halides significantly less reactive than alkyl halides towards nucleophilic substitution?

Answer: B

💡 Solution & Explanation

In aryl halides, the lone pairs of electrons on the halogen atom participate in delocalization with the benzene ring. This $p-\pi$ resonance imparts partial double-bond character to the $C-X$ bond, making it difficult to cleave.

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