Consider the redox reaction in acidic medium: When this equation is perfectly balanced with the smal — Redox Reactions and Volumetric Analysis Chemistry Question
Question
Consider the redox reaction in acidic medium: $MnO_4^- + H_2O_2 + H^+ \rightarrow Mn^{2+} + O_2 + H_2O$ When this equation is perfectly balanced with the smallest whole-number coefficients, what is the stoichiometric coefficient of $H^+$?
Answer: 6
💡 Solution & Explanation
Oxidation: $H_2O_2 \rightarrow O_2 + 2H^+ + 2e^-$ (multiply by 5). Reduction: $MnO_4^- + 8H^+ + 5e^- \rightarrow Mn^{2+} + 4H_2O$ (multiply by 2). Combining gives $2MnO_4^- + 16H^+ + 5H_2O_2 \rightarrow 2Mn^{2+} + 8H_2O + 5O_2 + 10H^+$. Cancelling $H^+$ on both sides yields a net of $6H^+$ on the reactant side.
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